Name: 
 

Final Exam Spring 2014 Chemistry



Multiple Choice
Identify the choice that best completes the statement or answers the question.
 
 
nar001-1.jpg
 

 1. 

Based on the periodic table shown, elements from columns B and E will combine in which ratio?
a.
2B:3E
c.
3B:2E
b.
3B:1E
d.
These elements will not combine.
 

 2. 

Group 13 elements tend to acquire which charge when they form ions?
a.
+3
c.
+5
b.
-5
d.
-3
 

 3. 

How many total electrons must be transferred to form one formula unit of the compound Al2O3?
a.
2
c.
6
b.
3
d.
5
 

 4. 

Which is a correct statement of bond strength?
a.
Compounds with smaller atoms have weaker bond strength.
b.
Compounds with a higher total number of atoms in the compound have greater bond strength.
c.
Compounds containing atoms with greater charges have higher bond strength.
d.
Compounds with a more negative lattice energy have lower bond strength.
 

 5. 

Which is the correct name for the compound CaClO2?
a.
Calcium Chloride
c.
Calcium Chlorite
b.
Calcium Chloroxide
d.
Calcium Chlorate
 

 6. 

Which combination of bonds is present in this molecule?

O = O
a.
1 sigma bond only
c.
2 pi bonds
b.
1 sigma bond and 1 pi bond
d.
1 sigma bond and 2 pi bonds
 

 7. 

Which exception to the octet rule is shown by this molecule?
mc007-1.jpg
a.
uneven number of valence electrons
c.
expanded octet
b.
suboctet
d.
coordinate covalent bond
 

 8. 

How many single covalent bonds can halogens form?
a.
1
c.
3
b.
2
d.
4
 

 9. 

How many valence electrons are available in the ion NO3-?
a.
16
c.
22
b.
9
d.
24
 

 10. 

How many pi bonds are there in a triple covalent bond?
a.
1
c.
3
b.
2
d.
4
 

 11. 

What is the correct ratio of coefficients to balance this chemical equation?
mc011-1.jpg
a.
1:2:3
c.
2:4:3
b.
1:2:1.5
d.
1:1:2
 

 12. 

How many total atoms are in 3Na2SO4?
a.
21
c.
24
b.
10
d.
18
 

 13. 

Which type of reaction involves one element and one compound reacting?
a.
decomposition
c.
single replacement
b.
double replacement
d.
synthesis
 

 14. 

Which substances have the same empirical formula?
SampleFormula
1CH3OH
2CH2O
3C6H12O6
4C2H4O2
5C7H5O2
6C8H8
a.
Samples 1, 2, and 4
c.
Samples 1 and 3
b.
Sample 1 and 4
d.
Samples 2 and 3
 

 15. 

Which is the correct empirical formula for this substance?
ElementPercent Composition
C37.5%
H12.5%
O50.00%
a.
CH4O
c.
C3H12O3
b.
CHO
d.
C3H4O
 

 16. 

Which is the percent composition of bromine in the compound NaBr?
a.
81.6%
c.
84.1%
b.
79.9%
d.
77.7%
 

 17. 

Which term is described as the percent by mass of any element in a compound?
a.
hydrate
c.
empirical formula
b.
molecular formula
d.
percent composition
 

 18. 

Which is true of the reaction shown below?
mc018-1.jpg
a.
The mole ratio of this reaction is 6:5:6.
b.
Two molecules of Substance Y will be left over when this reaction goes to completion.
c.
Substance Y is the limiting reagent in this reaction.
d.
The addition of more molecules of Substance X will not affect the amount of Substance Z that can be made.
 

 19. 

How many moles of Cu are needed to react with 5.8 moles of AgNO3?
Cu + 2 AgNO3 ® Cu(NO3)2 + 2 Ag
a.
2.9 moles
c.
5.8 moles
b.
3.8 moles
d.
11.6 moles
 

 20. 

A reaction was predicted to produce 32.4 grams of a compound. When the product was measured, there were only 26.1 grams made. What is the percent yield of this reaction?
a.
80.6%
c.
24.1%
b.
6.3%
d.
58.5%
 

 21. 

How many grams of Fe3O4 are required to react completely with 300 grams of H2?
mc021-1.jpg 
a.
2096 g
c.
8681 g
b.
1.54 g
d.
37.5 g
 

 22. 

What principle is illustrated in the figure?
mc022-1.jpg
a.
Boyle’s Law
c.
Ideal Gas Law
b.
Charles’s Law
d.
Scientific Theory
 

 23. 

According to Gay-Lussac’s law:
a.
pressure is inversely proportional to volume at constant temperature.
b.
pressure is directly proportional to temperature at constant volume.
c.
volume is inversely proportional to temperature at constant pressure.
d.
volume is directly proportional to temperature at constant pressure.
 

 24. 

When a milkshake is taken in through a straw at a pressure of 0.071 atm, the straw contains 5.0 mL of liquid. How much liquid is consumed at 0.092 atm?
a.
0.10 mL
c.
6.3 mL
b.
3.9 mL
d.
7.8 mL
 

 25. 

A welding torch requires 3200 L of ethylene gas at 3.00 atm. What will be the pressure of the gas if ethylene is supplied by a 250.0-L tank?
a.
0.231 atm
c.
38.4 atm
b.
2.34 atm
d.
45.4 atm
 

 26. 

A/An _____ is a substance that slows down the rate of a reaction.
a.
catalyst
c.
reactant
b.
inhibitor
d.
product
 

 27. 

If a collision between molecules is very gentle, the molecules are
a.
more likely to be oriented favorably.
b.
less likely to be oriented favorably.
c.
likely to react.
d.
likely to rebound without reacting.
 

 28. 

A _____ is produced when a base accepts a hydrogen ion from an acid.
a.
conjugate acid
c.
acid
b.
conjugate base
d.
base
 

 29. 

In the Bronsted-Lowry model of acids and bases, an _____ is a hydrogen donor and a _____ is a hydrogen acceptor.
a.
acid, base
c.
conjugate acid, conjugate base
b.
base, acid
d.
conjugate base, conjugate acid
 

 30. 

A solution that contains equal concentrations of hydrogen and hydroxide ions is _____.
a.
an acid
c.
neutral
b.
a base
d.
ionized
 

 31. 

Calculate the hydrogen ion concentration of an aqueous solution, given the pOH of the solution is 4.50 and the ion product constant for water, KW, is 1.00 ´ 10–14.
a.
3.16 ´ 10–10 M
c.
3.16 ´ 10–5 M
b.
3.16 ´ 10–9 M
d.
3.16 ´ 10–7 M
 

 32. 

An aqueous solution has a pH of 2.7 at 298 K. Calculate the pOH of the aqueous solution.
a.
9.3
c.
17
b.
12
d.
11
 

 33. 

What is the oxidation number of chlorine in NaCl?
a.
-2
c.
0
b.
-1
d.
+1
 

 34. 

_____ numbers are based on the distribution of electrons in a molecule.
a.
coefficient
c.
electron
b.
oxidation
d.
chemical
 

 35. 

_____A species whose oxidation number _____ is oxidized.
a.
increases
c.
stays the same
b.
decreases
d.
is neutral
 

 36. 

Calculate the hydrogen ion concentration of an aqueous solution, given the concentration of hydroxide ions is 1 ´ 10-5 M and the ion constant for water is 1 ´ 10-14.
a.
mc036-1.jpg
c.
mc036-3.jpg
b.
mc036-2.jpg
d.
mc036-4.jpg
 

 37. 

When acids react with metals, they produce _____ gas.
a.
hydrogen
c.
sulfur
b.
nitrogen
d.
oxygen
 

 38. 

Calculate pH of an aqueous solution of hydrogen chloride acid. Given the hydrogen ion concentration is 8.75 ´ 10–9 M.
a.
7.85
c.
8.06
b.
7.81
d.
7.77
 

 39. 

Calculate the pOH of a 0.410 M Ba(OH)mc039-1.jpg solution.
a.
mc039-3.jpg
c.
mc039-5.jpg
b.
mc039-4.jpg
d.
mc039-6.jpg
 

Short Answer
 

 40. 

Elements in groups 1A and 2A in the periodic table form positively charged ions by loss of electrons. What will be the charge on an atom, if it belongs to group 1A?
 

 41. 

Which kind of molecular shape will this molecule have? Explain how you can tell from the Lewis structure.
sa041-1.jpg
 

 42. 

Why is it necessary to use prefixes in naming covalent compounds?
 

 43. 

Infer three pieces of evidence that a chemical reaction is taking place in the pictures shown.

sa043-1.jpg
 

 44. 

Fill in the missing conversion factors in the diagram.
sa044-1.jpg
 

 45. 

When converting a temperature from Celsius degrees to Kelvin degrees, what number must be added to the Celsius temperature?
 

Completion
Complete each statement.
 

 46. 

An ionic bond results due to the ____________________ attraction between two oppositely charged ions.
 

 

 47. 

The name of the anion co047-1.jpg is ____________________.
 

 

 48. 

The name of the acid HI is ____________________ acid.
 

 

 49. 

A chemical reaction in which oxygen combines with a substance and releases energy in the form of heat and light is called a(n) ____________________ reaction.
 

 

 50. 

A reaction in which the atoms of one element replace the atoms of another element in a compound is called a(n) ____________________ reaction.
 

 

 51. 

In an aqueous solution, the solvent is always ____________________.
 

 

 52. 

The molar mass of carbon tetrachloride is ____________________ g/mol.
 

 

 53. 

A compound that has specific number of water molecules bound to its atoms is known as a(n) ____________________.
 

 

 54. 

A ____________________ is the species produced when a base accepts a hydrogen ion from an acid.
 

 

 55. 

In the ____________________ model of acids and bases, an acid is a hydrogen-ion donor and a base is a hydrogen-ion acceptor.
 

 

 56. 

When an atom ____________________ electrons, its oxidation number decreases.
 

 

 57. 

In chemistry, a ____________________ is any kind of chemical unit involved in a process.
 

 

 58. 

A reaction mechanism for the formulation of NO2 is given as:
(a)2NOco058-1.jpg co058-2.jpg Nco058-3.jpgOco058-4.jpgfast step
(b)Nco058-5.jpgOco058-6.jpg + Hco058-7.jpg co058-8.jpg Nco058-9.jpgO + Hco058-10.jpgOslow step
(c)Nco058-11.jpgO + Hco058-12.jpg co058-13.jpg Nco058-14.jpg + Hco058-15.jpgOfast step
From the above information we can infer that ____________________ is the rate-determining step.
 

 

 59. 

The ____________________ of a reaction is defined as the sum of powers of the concentration in the rate law.
 

 

 60. 

In the reaction, co060-1.jpg, the mechanism is:
co060-2.jpg

The intermediate compound for the mechanism above is ____________________.
 

 

Problem
 

 61. 

Why is PClpr061-1.jpg an exception to the octet rule, while PClpr061-2.jpg is not?
 

 62. 

What is the percent yield for a reaction if the theoretical yield of C6H12 is 21 g and the actual yield recovered is only 3.8 g?
 

 63. 

A 6.32-L football is filled with air at 1.90 atm at 25.1°C. At the same temperature, the volume of the football is reduced to 3.49 L. What is the pressure of air in the ball?
 

 64. 

Calculate the temperature of 2.0 moles of a gas occupying a volume of 5.0 L at 2.46 atm.
 

 65. 

When nitrogen gas reacts with hydrogen gas, ammonia gas is formed. How many grams of hydrogen gas are required to react completely with 3.5 L of nitrogen at STP?
 

 66. 

If the pressure exerted by a gas at 27.0°C in a vessel of volume 0.050 L is 4.00 atm, how many moles of the gas are present?
 

 67. 

Calculate the volume of the vessel that holds 0.30 moles of a gas at STP.
 

 68. 

For a hypothetical reaction, 1.2A + 2.5K + 4.4X, give the rate law expression and calculate the order of the reaction.
 

 69. 

Determine the net change of the oxidation number of silver in the following redox reaction, given the oxidation number of sulfur in Silver sulfide is –2.
Silver + Sulfurpr069-1.jpg Silver sulfide
 

 70. 

When lead sulfide reacts with oxygen, the precipitate of lead oxide is formed and sulfur dioxide gas is evolved. Balance the redox equation by the half-reaction method.
PbS + O2 pr070-1.jpg PbO + SO2
The net ionic equation for the redox reaction is
S2– + O2 pr070-2.jpg SO2 + O2–
 



 
Check Your Work     Start Over